Mindblown: a blog about philosophy.
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Approach to synthesis
The range of compounds that are capable of being synthesized is essentially limitless. In practice, the synthesis of a preselected compound is made possible by particular functional groups undergoing transformations that, while they are dependent on the conditions applied to the compound, are largely independent of the structure of the remaining part of the molecule. Thus, the combination…
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Chemical synthesis
Chemical synthesis is concerned with the construction of complex chemical compounds from simpler ones. A synthesis usually is undertaken for one of three reasons. The first reason is to meet an industrial demand for a product. For example, ammonia is synthesized from nitrogen and hydrogen and is used to make, among other things, ammonium sulfate, employed as a fertilizer; vinyl chloride is made from ethylene and is…
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Polyfunctional compounds
Although each of the functional groups introduced above has a characteristic set of favoured reactions, it is not always possible to predict the properties of organic compounds that contain several different functional groups. In polyfunctional organic compounds, the functional groups often interact with one another to impart unique reactivity patterns to the compounds. As chemistry…
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Carboxylic acids
The conjunction of a carbonyl and a hydroxyl group forms a functional group known as a carboxyl group. The hydrogen of a carboxyl group can be removed (to form a negatively charged carboxylate ion), and thus molecules containing the carboxyl group have acidic properties and are generally known as carboxylic acids. Vinegar is a 5 percent solution…
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Aldehydes and ketones
When an oxygen atom forms a double bond to a carbon atom, a carbonyl functional group is obtained. The carbon atom of a carbonyl group is bonded to two other atoms in addition to the oxygen atom. A wide range of functional groups are produced by the presence of different atomic groupings on the carbon of the…
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Halides
Halides, or organohalides, are compounds that contain a halogen atom (fluorine, chlorine, bromine, or iodine) bonded to a carbon atom by a polar bond. The slightly positive charge that exists on the carbon atom in carbon-halogen bonds is the source of reactivity of halides. A wide variety of organohalides have been discovered in marine organisms,…
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Amines
Amines are functional group compounds that contain at least one nitrogen atom bonded to hydrogen atoms or to alkyl or aryl groups. If the substituents (other than hydrogen atoms) are alkyl groups, the resulting compounds are termed alkyl amines. If one or more substituents is an aryl group, the compounds are termed aryl amines. Amines are commonly…
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Thiols
A thiol is structurally similar to an alcohol but contains a sulfur atom in place of the oxygen atom normally found in an alcohol. The outstanding feature of thiols is their foul smell. The simplest thiol is hydrogen sulfide, H2S, the sulfur analog of water. It can be detected by the human nose at a concentration of a…
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Ethers and epoxides
An organic molecule in which an oxygen atom is bonded to two carbon atoms through two sigma bonds is known as an ether. Ether molecules occur widely in nature. Diethyl ether was once widely used as an anesthetic. An aromatic ether known as Nerolin II (2-ethoxynaphthalene) is used in perfumes to impart the scent of orange…
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Alcohols and phenols
An oxygen atom normally forms two σ bonds with other atoms; the water molecule, H2O, is the simplest and most common example. If one hydrogen atom is removed from a water molecule, a hydroxyl functional group (―OH) is generated. When a hydroxyl group is joined to an alkane framework, an alcohol such as ethanol, is produced. When the hydroxyl group…
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