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  • Alkenes

    Organic compounds are termed alkenes if they contain a carbon-carbon double bond. The shared electron pair of one of the bonds is a σ bond. The second pair of electrons occupies space on both sides of the σ bond; this shared pair constitutes a pi (π) bond. A π bond forms a region of increased electron density…

  • Alkanes

    Alkanes are compounds that consist entirely of atoms of carbon and hydrogen (a class of substances known as hydrocarbons) joined to one another by single bonds. The shared electron pair in each of these single bonds occupies space directly between the two atoms; the bond generated by this shared pair is known as a sigma…

  • Functional groups

    Chemists observed early in the study of organic compounds that certain groups of atoms and associated bonds, known as functional groups, confer specific reactivity patterns on the molecules of which they are a part. Although the properties of each of the several million organic molecules whose structure is known are unique in some way, all…

  • Carbon bonding

    The carbon atom is unique among elements in its tendency to form extensive networks of covalent bonds not only with other elements but also with itself. Because of its position midway in the second horizontal row of the periodic table, carbon is neither an electropositive nor an electronegative element; it therefore is more likely to share…

  • Historical developments

    When chemistry took on many of the characteristics of a rational science at the end of the 18th century, there was general agreement that experiment could reveal the laws that governed the chemistry of inanimate, inorganic compounds. The compounds that could be isolated from living organic entities, however, appeared to have compositions and properties entirely different from…

  • organic compound

    Organic compound, any of a large class of chemical compounds in which one or more atoms of carbon are covalently linked to atoms of other elements, most commonly hydrogen, oxygen, or nitrogen. The few carbon-containing compounds not classified as organic include carbides, carbonates, and cyanides. In general, organic compounds are substances that contain carbon (C), and carbon atoms provide the key structural framework that generates the vast diversity of organic compounds.…

  • anhydride

    Anhydride, any chemical compound obtained, either in practice or in principle, by the elimination of water from another compound. Examples of inorganic anhydrides are sulfur trioxide, SO3, which is derived from sulfuric acid, and calcium oxide, CaO, derived from calcium hydroxide. Sulfur trioxide and other oxides formed by the removal of water from an acid are often called acid anhydrides, whereas those such as…

  • tungsten carbide

    Tungsten carbide, an important member of the class of inorganic compounds of carbon, used alone or with 6 to 20 percent of other metals to impart hardness to cast iron, cutting edges of saws and drills, and penetrating cores of armour-piercing projectiles. Tungsten carbide is a dense, metallike substance, light gray with a bluish tinge, that decomposes, rather than melts, at 2,600° C…

  • sulfate

    Sulfate, any of numerous chemical compounds related to sulfuric acid, H2SO4. One group of these derivatives is composed of salts containing the sulfate ion, SO42-, and positively charged ions such as those of sodium, magnesium, or ammonium; a second group is composed of esters, in which the hydrogen atoms of sulfuric acid have been replaced by carbon-containing combining…

  • Polymer chemistry

    The study of such materials lies within the domain of polymer chemistry. The investigation of natural polymers overlaps considerably with biochemistry, but the synthesis of new polymers, the investigation of polymerization processes, and the characterization of the structure and properties of polymeric materials all pose unique problems for polymer chemists. Polymer chemists have designed and synthesized polymers that…

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