Mindblown: a blog about philosophy.

Adenine, organic compound belonging to the purine family, occurring free in tea or combined in many substances of biological importance, including the nucleic acids, which govern hereditary characteristics of all cells. Partial decomposition of ribonucleic and deoxyribonucleic acids yields mixtures from which the compounds adenylic acid and deoxyadenylic acid, respectively, may be separated. These acids, called nucleotides, are phosphate esters of adenosine and deoxyadenosine, which…

A carbon atom (and therefore the molecule in which it occurs) becomes oxidized if it loses electron density during a reaction or becomes reduced if it gains electron density. A carbon atom loses electron density when it bonds to a more electronegative atom and gains electron density when it bonds to a less electronegative atom. The most…

For much of organic chemistry, an acid may be defined as a compound that can transfer a proton (H+) to a base, and a base may be defined as any entity with an unshared pair of electrons (and therefore capable of accepting a proton). In acid-base reactions a proton is transferred from an acid to a…

The formation of a single bond between two molecules, or two parts of the same molecule, accompanied by the elimination of water (or another small molecule such as an alcohol) is a condensation reaction. Many polymerization reactions are condensation reactions. For example, the polymer nylon-6,6 is produced by the repeated condensation of hexanedioic acid with hexamethylenediamine.

The scission (or cleavage) of a molecule by reaction with water, with insertion of the elements of water into the final products, is called hydrolysis. An example is the acid-catalyzed hydrolysis of ethyl acetate. This reaction is typical of reversible reactions that do not go to completion. When one mole (the quantity with a weight…

The addition of one molecule to another to give a single new molecule constitutes an important class of reactions. Illustrative is the addition of chlorine to ethylene to give the dichloroethane used for the industrial production of vinyl chloride. Alcohols are commonly made by the addition of water to alkenes, as in the preparation of 2-propanol.

The formation of new bonds in a molecule by the removal of atoms takes place in an elimination reaction. These reactions are often responsible for the formation of double bonds, as in the formation of an alkene from an alcohol by the action of concentrated sulfuric acid, and for the thermal elimination of hydrogen chloride to make chloroethene.

The simple replacement of one atom or group of atoms in a molecule by a second atom or group of atoms is called a substitution reaction. An illustrative example is the conversion of benzyl bromide to benzyl alcohol, using a solution of sodium hydroxide in water. In this reaction the bromine atom of the benzyl bromide has been replaced by the hydroxyl group of…

The electronic features of functional groups are responsible for the types of reactions that are characteristic of each group. Because there is a great deal of similarity in the electronic characteristics of the different functional groups, there is a corresponding similarity in the types of reaction that different groups undergo. Just as the properties of…

Mass spectrometry differs from the types of spectroscopy previously discussed because the molecular information that the technique provides does not depend on absorption of electromagnetic radiation. In a mass spectrometer, molecules are converted to charged fragments called ions, which are then separated according to their masses. The chart that records the masses of the fragments…