A carbon atom (and therefore the molecule in which it occurs) becomes oxidized if it loses electron density during a reaction or becomes reduced if it gains electron density. A carbon atom loses electron density when it bonds to a more electronegative atom and gains electron density when it bonds to a less electronegative atom. The most common oxidation reactions occur when carbon atoms bond to oxygen (the process for which the reaction type is named) or when hydrogen atoms are removed from carbon. Conversely, the most common reduction reactions occur when hydrogen is added to a carbon atom or when oxygen is removed is from a carbon atom. Because an increase of electron density at one atom must always be accompanied by a decrease of electron density at a different atom, an oxidation reaction always occurs in tandem with a reduction reaction. The combustion of methane is a simple example. Another example is the oxidation of ethanol to acetic acid, which can be used by common breath-analyzer kits to measure the alcohol level in a person’s breath on the basis of the visible colour changes that occur as orange potassium dichromate is reduced to green chromium (III) sulfate. Humans, and all other aerobic organisms, require oxygen for the metabolic oxidation of foodstuffs. The fully oxidized product of such metabolic oxidation is carbon dioxide, which is exhaled via the lungs.
Oxidation-reduction reactions
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